Is paint a solution colloid or suspension

An emulsifying agent (emulsifier) is any substance that keeps the parts of an emulsion mixed together. For example if we mix oil and water a suspension will form that over time separates. But now, if we add a few drops and shake the mixture the oil and water will stay mixed much longer.

Oil-based paints tend to separate into layers over time. The pigment molecules are suspended in a solvent of linseed oil and mineral spirits. Oil-based paints are suspensions. Water-based paints such as latex paint are colloids.

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  1. Suspensions
  2. Colloids
    1. Tyndall Effect
    2. Examples of Colloids
    3. Emulsions
  3. Supplemental Resources
  4. Contributors and Attributions

Learning Outcomes

  • Describe the properties of a suspension.
  • Describe the properties of a colloid.
  • Distinguish among suspensions. colloids, and solutions.

Suspensions

Take a glass of water and throw in a handful of sand or dirt. Stir it and stir it and stir it. Have you made a solution? Sand and dirt do not dissolve in water, and, though it may look homogenous for a few moments, the sand or dirt gradually sinks to the bottom of the glass (see figure below). Some medications are delivered as suspensions and must be mixed well before the doses measured to make sure the patient is receiving the correct amount of medication.

Is paint a solution colloid or suspension
Figure \(\PageIndex{1}\): A mixture of sand and water forms a suspension.

A suspension is a heterogeneous mixture in which some of the particles settle out of the mixture upon standing. The particles in a suspension are far larger than those of a solution, so gravity is able to pull them down out of the dispersion medium (water). The diameter for the dispersed particles in a suspension, such as the sand in the suspension described above, is typically at least 1000 times greater than those in a solution. Unlike a solution, the dispersed particles can be separated from the dispersion medium by filtering. Suspensions are considered heterogeneous because the different substances in the mixture will not remain uniformly distributed if they are not actively being mixed.

Colloids

A colloid is a heterogeneous mixture in which the dispersed particles are intermediate in size between those of a solution and a suspension. The particles are spread evenly throughout the dispersion medium, which can be a solid, liquid, or gas. Because the dispersed particles of a colloid are not as large as those of a suspension, they do not settle out upon standing. The table below summarizes the properties and distinctions between solutions, colloids, and suspensions.

Table \(\PageIndex{1}\): Properties of Solutions, Colloids, and SuspensionsSolutionColloidsSuspensionsHomogeneousHeterogeneousHeterogeneousParticle size: \(0.01\)-\(1 \: \text{nm}\); atoms, ions or moleculesParticle size: \(1\)-\(1000 \: \text{nm}\), dispersed; large molecules or aggregatesParticle size: over \(1000 \: \text{nm}\), suspended: large particles or aggregatesDo not separate on standingDo not separate on standingParticles settle outCannot be separated by filtrationCannot be separated by filtrationCan be separated by filtrationDo not scatter lightScatter light (Tyndall effect)May either scatter light or be opaque

Colloids are unlike solutions because their dispersed particles are much larger than those of a solution. The dispersed particles of a colloid cannot be separated by filtration, but they scatter light, a phenomenon called the Tyndall effect.

Tyndall Effect

Colloids are often confused with true homogenous solutions because the individual dispersed particles of a colloid cannot be seen. When light is passed through a true solution, the dissolved particles are too small to deflect the light. However, the dispersed particles of a colloid, being larger, do deflect light (see figure below). The Tyndall effect is the scattering of visible light by colloidal particles. You have undoubtedly "seen" a light beam as it passes through fog, smoke, or a scattering of dust particles suspended in air. All three are examples of colloids. Suspensions may scatter light, but if the number of suspended particles is sufficiently large, the suspension may simply be opaque, and the light scattering will not occur.

Is paint a solution colloid or suspension
Figure \(\PageIndex{2}\): Light passes through a colorless solution and is not scattered. When it passes through a diluted milk solution, the light is scattered by colloidal particles, an observation of the Tyndall effect. The Tyndall effect allows sunlight to be seen as it passes through a fine mist.

Examples of Colloids

Listed in the table below are examples of colloidal systems, most of which are very familiar. Some of these are shown below (see figure below). The dispersed phase describes the particles, while the dispersion medium is the material in which the particles are distributed.

Table \(\PageIndex{2}\): Classes of ColloidsClass of ColloidDispersed PhaseDispersion MediumExamplesSol and gelsolidliquidpaint, jellies, blood, gelatin, mudSolid aerosolsolidgassmoke, dust in airSolid emulsionliquidsolidcheese, butterLiquid emulsionliquidliquidmilk, mayonnaiseLiquid aerosolliquidgasfog, mist, clouds, aerosol sprayFoamgassolidmarshmallowFoamgasliquidwhipped cream, shaving cream
Is paint a solution colloid or suspension
Figure \(\PageIndex{3}\): Some common colloids (A) gelatin dessert, (B) smoke (solid aerosol), (C) butter (solid emulsion), (D) mayonnaise (liquid emulsion), (E) fog (liquid aerosol), (F) marshmallows (foam), (G) whipped cream (foam)

Emulsions

Butter and mayonnaise are examples of a class of colloids called emulsions. An emulsion is a colloidal dispersion of a liquid in either a liquid or a solid. A stable emulsion requires an emulsifying agent to be present. Mayonnaise is made in part of oil and vinegar. Since oil is nonpolar, and vinegar is a polar aqueous solution, the two do not mix and would quickly separate into layers. However, the addition of egg yolk causes the mixture to become stable and not separate. Egg yolk is capable of interacting with both the polar vinegar and the nonpolar oil. The egg yolk is called the emulsifying agent. Soap acts as an emulsifying agent because one end of a soap molecule is polar, and the other end is nonpolar. This allows the grease to be removed from your hands or your clothing by washing with soapy water.

Supplemental Resources

  • Types of Mixtures - Solutions, Suspensions, Colloids: www.edinformatics.com/math_sc.../mixtures.html

Contributors and Attributions

  • Allison Soult, Ph.D. (Department of Chemistry, University of Kentucky)


This page titled 7.6: Colloids and Suspensions is shared under a CK-12 license and was authored, remixed, and/or curated by CK-12 Foundation via source content that was edited to the style and standards of the LibreTexts platform; a detailed edit history is available upon request.

Is paint a suspension or solution?

paint is always a suspension...a dispersion of finely divided pigment particles in a medium.

Is paint considered a solution?

Paints are not true solutions as there is no true solute that is dissolved in a solvent. The particle size is too large to be considered a true solution (solution particles are typically less than 1 nm in dimension). A solution is a heterogeneous mixture, and paint is not.

Is paint a mixture or a solution?

Paint, containing a liquid solution and a dispersed solid pigment, is a mixture. It is a mixture since it contains two or more substances: the solution (a liquid containing solutes) and a dispersed solid pigment. This substance has only one phase.

What type of colloid is paint?

Paints or surface coatings are complex, multi-phase, colloidal systems that are ap- plied as a continuous layer to a surface [1]. A paint usually contains pigmented materials to distinguish it from clear films that are described as lacquers or var- nishes.